- 1200 The Incas rule
- 1538 Spain conquers Bolivia, which becomes part of the vice-royalty of Peru
- 1545 Silver is discovered in the Cerro Rico mountain in Potosi and Spain uses indigenous and black slaves as workers.
- 1561 Santa Cruz was founded by the Spaniard Nuflo de Chavez
- 1810 Overthrow of the king of Spain by Napoleon
- 1819 General Simon Bolivar defeats Bolivian royalist forces in the Battle of Boyaca on August 7 and the Republic of Colombia (also known as Gran Colombia) is proclaimed on December 17, consisting of Colombia, Venezuela, and Ecuador
- 1825 Bolivia declared its independence from Peru liberated by Simon Bolivar, for whom the Bolivian nation was later named
- 1907 Butch Cassidy and the Sundance Kid went to Bolivia where they were gunned down by Bolivian soldiers after robbing a mine
- 1928 Oil was discovered in the foothills of the Andes at the western Bolivian region of the Chaco
- 1932-1935 The Chaco War with Paraguay - ironically it was discovered that there was no oil after all
- 1942 Victor Paz Estensorro founded the National Revolutionary Movement
- 1952-1956 Victor Paz Estensorro founder of the National Revolutionary Movement served his first of four terms as Bolivian president
- 1967 Che Guevara was executed while attempting to incite revolution in Bolivia
- 1971-1978 Colonel Hugo Banzer Suarez ruled Bolivia as the military dictator
- 1982-1985 Hernan Siles Zuazo (1913-1996) became Bolivian president again and restored democracy after 18 years of military rule
- 2006 The first indigenous Bolivian president takes office in January promising radical changes using his socialist agenda.
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